Dr Mrs Vandertramp Easy

Hemispheric yamadori - Second step! Pino

continue my work on this plant that is one of my best ...
After about 14 months the plant has only one crop a lot vegetated and appeared strong and vigorous for a new step of setting up and spinning ...
Here it is:







So removing the line where noted, new spinning, cleaning of grain, more liquid tar jin (not to be too white to dry) and new setting ...
This is the result:





Now we will be the choice of the vessel, which is not easy given the particular characteristics of the plant ...
but the good thing is that too!
I leave you with some images of dry and apex of the plant ..








To be continued ....

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the basic structures of Cardenoide and bufadienolite

the basic structures of Cardenoide and bufadienolite

derive from cholesterol through a degradation (preceded by an oxidation like all biological degradation processes) of the former are only the C20 cholesterol and C21. The products are either Digitossigenina (see image above) by addition of acetyl-CoA or Bufalina (different only in the presence of a cycle to 6 instead of 5) by addition of ossoacetil-CoA.

• Bile Acids : present as salts in the bile, the Their function is to fat emulsion in relation to thus facilitate digestion. Cholic acid is the main representative:

There is also acid deoxycholate, where instead there is a C7 to dell'ossidrile H:

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Scrophulariaceae against cholesterol

cardiocinetici Among the drugs, also known as cardio or cardenolidi, include some substances extracted from flowers, digital, common name for several plants of the genus Digitalis, the most important of which is Digitalis purpurea, Digitalis less important than the dawn and Digitalis lanata .

Family : Scrofulariaceae

Part used: leaves (Digitalis purpurea crowd FU)

Main components:

-cardiac glycosides: digitoxin, digitossigenina, gitalossigenina.

-digitanol-glycosides: digitalonina, digìnoside, digifolei

active derivatives are mainly two: the digoxin and digitoxin. The digitalis glycoside digitonin is another but has no effect on the heart and is mainly used for its power surfactant.

The mechanism of action must be taken into account the fact that these derivatives are cellular poisons: their pharmacological action comes from this, but of course this also leads to inherent dangers in the use of these substances. I have therefore digitalis high efficacy, but have a high toxicity and prolonged in time, which only recently was able to revert to the use of antidotes acting drugs, which opposes any action in the event of toxic overdose.

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terpenotiche

For terpenoid saponins it starts from squalene, squalene or better in the oxidized form until you get to Lupeol, amirina α and β, taraxsterolo, ie C30, triterpenes in all respects.

• cardiac glycosides: molecules of this group of substances are characterized by the "active" structure represented by a steroid and phenanthrene (a ciclopentanoperidrofenantrene), which is tied at one end and a lactone ring to another, position 3, a sequence of sugars (digitossosio)

is for the presence of these sugars that these molecules are known as cardiac glycosides:

cardiocinetici Among the drugs, also known as cardio or cardenolidi, include some substances extracted from flowers, digital, common name for several plants of the genus Digitalis the most important of which is Digitalis purpurea, less important than the type lis dawn and Digitalis lanata.

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For saponins steroidal saponins (eg Dioscina) is from cholesterol:

For steroidal saponins (eg Dioscina) is from cholesterol:
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where you can accumulate steroids?: are the residues of the plant saponin zuccherri

Residues sugars are present in varying numbers from one to six units. The sapogenins have, however, a more complex structure, due to two groups:

1.Triterpenico;

2.Steroideo.

The core triterpene saponins (such as licorice or glycyrrhizin dell'ippocastano escin) has a pentacyclic structure 0 to 3 carbon atoms while the steroid nucleus to have a basic with 27 carbons (often the aliphatic chain is transformed into two heterocyclic rings).

In therapy, at present, the saponins of some plants is recognized anti-inflammatory activity, healing (as in licorice) and anti-edema (as in 'horse chestnut).

saponins are often used in industry for the subsequent production of steroid hormones (such as, for example, testosterone and cortisol)

CORTISOL

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Classification of functions in purifying

The plant has properties primarily saponin detoxifying, diuretic, tonic and sweat. Saponin can be prepared with a good shampoo for fragile hair. The high content of saponins have earned the name for this plant was used by the people as detergent.

Common name: Saponin

Family: Cariofillacee

Active ingredients:

-saponins

-mucilage

-resins

saponin from the plant is obtained a decoction that can be used as a strengthening shampoo for fragile hair and brittle, or to cleanse the delicate skin.

With the infusion of saponin you can also rinse the skin affected by acne or psoriasis.

Trivia: saponin is a substance found in stems, leaves and in especially in the roots, through which just exercising his gentle but deep cleansing power.

A decoction of soap, made by boiling the plant in different parts of the rain water is very suitable to restore the splendor of ancient fabrics whose colors have been dimmed by dust and time.

Structurally, saponins are formed from the combination of residual sugar (as glucose, fructose, galactose, arabinose or other) with a sugar molecule is not known aglycone (in this case also sapogenins). This particular structure is responsible for the of the detergent saponin in the section form a water-soluble sugars and the aglycone appears to be soluble.

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Steroids: What

Classification of Steroids:

Saponins: glycosides of plant origin, which take their name from Saponaria officinalis, which were found to the first time.

I can lower the surface tension in aqueous solutions, are able to form colloidal solutions and foaming can be used as emulsifiers.
injecting injection of these compounds causes hemolysis.

The oral intake, however, does not produce this poison because the hemolytic activity of saponins is expressed only if the molecule remains intact, which does not take place during digestion because it is split into two components .
In cold-blooded animals and fish are toxic saponins in each case for which in the past, plants containing these substances were used as poisons for hunting.
saponins are believed to be used by plants as defense systems against pathogens, especially fungi. In some cases, they are already present at other times of the precursors are synthesized by in case the plant has suffered damage.

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attorney cholesterol?

all 19 steps leading to cholesterol: being a lipid, is poorly soluble in water and be transported into the bloodstream requires, therefore, to bind to specific lipoproteins. Cholesterol binds mainly ll low-density lipoprotein or LDL (so-called bad cholesterol). It is estimated that approximately 60-80% of the total cholesterol is bound to LDL.

The excess cholesterol in these lipoproteins bound tends to accumulate on the endothelium of arteries, forming dense aggregates growing up to generate real plaques, called atheromas.

These plaques are losing the natural elasticity of the arteries and can cause severe damage especially to the heart (heart attack) or brain (stroke).

The good cholesterol is represented by HDL (high density lipoprotein) that clean the arteries by capturing and transferring excess cholesterol to the tissues (especially liver), where it is disposed.

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organic chemistry of steroids: cholesterol and its synthesis in the body

I the cholesterol in the body is formed from squalene (Terpene found the first time in a shark but is very present in organisms). Squalene is formed from acetyl-CoA:

PHASE 1: 3 x AcetilCoA produce Mevalonate

• L 'escapes from Acetyl-CoA mitochondria with citrate shuttle

• The first two reactions are the same views in the synthesis of ketone bodies

• The two enzymes are involved cytosol

Step 2: mevalonate merged form 'active isoprenoids (isopentenyl pyrophosphate)

So:

• The p irofosfato helps keep these compounds in solution otherwise insoluble in H 2 O

• The third phosphate group serves as the acceptor hydroxyl group-OH of mevalonate, which is removed in the dephosphorylation accompanying decarboxylation reaction in the fourth

• C atom is lost (as CO 2 )

So:

HMG-CoA reductase catalyzes the limiting step in the way of cholesterol synthesis.

Step 3: 6 units' form isoprenoid squalene

2 molecules of farnesyl pyrophosphate bond Head injury - Head to PreSqualene pyrophosphate:

reduction that gives Squalene:

The transition from squalene to cholesterol requires the formation of lanosterol:

2 enzymes involved:

- squalene monooxygenase (epoxidase or) ( RE )

- cyclase, which catalyzes the reaction more complex enzyme known (about 20 steps)

The lanosterol and 'the first compound to have the 4-ring steroid nucleus

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chemistry of steroids: cholesterol in the life cycle of eukaryotes and prokaryotes

Cholesterol is an essential ingredient of the cell membrane of all animal cells:

- is inserted between two layers of phospholipids oriented with the-OH groups close to the polar heads of phospholipids, thus decreasing the fluidity of the mosaic (see fluid mosaic model) but increasing the mechanical stability and flexibility of the cells. In doing so, however, decreases the permeability to small water-soluble cell.

- Together with protein molecules cholesterol regulates the exchange of messenger substances through the cell membrane.

- Growth and cell division are not possible without cholesterol.

- Cholesterol is the basic substance for the synthesis of steroid hormones such as aldosterone, cortisone, testosterone, estradiol, etc.. (See adrenal glands and vitamin D).

- The cholesterol produced in the liver is used largely for the production of bile, a substance secreted into the duodenum, which serves to emulsify dietary lipids to make it absorbable by the small intestine.

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Chima steroids: the discovery of cholesterol and the etymology of the word

Cholesterol steroids is one of the most important: it is a lipid molecule consists of four rings of carbon atoms and an aliphatic tail as well as possible functional groups.

polycyclic The basic structure is called peridrofenantrene cyclopentane.

cholesterol comes from the greek word chole (bile) and stereos (solid), but was used for the first time in 1894. The ending-ol comes from the fact that the C3 ring carbon of the first [A] is a hydroxyl radical.

Its presence had been detected in the calculations of the gall bladder as early as 1784, but in 1975 the Nobel Prize John W. Cornforth said spatial orientation of the hydrogen atoms on the molecule.

Cholesterol is essential for animal life. Plants contain only slight traces cholesterol and other lipid substances structurally similar (fitosterine or phytosterols).

man produces most independent biosynthesis of cholesterol needed in adults between 1 and 2 grams per day. Only a small proportion (on average 0.1 to 0.3, up to 0.5 grams) is taken with food: most of the cholesterol metabolism occurs in the liver. The content of cholesterol in the human body is approx. 150 grams.

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Chemistry Steroids: 1 general part

Chemistry Steroids

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The term steroid identify any lipid with four fused carbon rings [policicloalifatici, A, B, C, D] and, often, an alkyl tail, steroids are cholesterol, sex hormones and adrenocortical hormones.

Steroids are biosintetizzati through the mevalonic acid pathway.

common feature is the presence of four rings of carbon atoms three to six cycles [A, B, C] and 1 cycle [D] a provision similar to the five atoms in ciclopentanoperidrofenantrene .

While the various steroids differ in the presence or absence of the carbon atoms identified by up to 18 and the functional groups present on the rest of the structure:

have known hundreds of different steroids, isolated from animal and plant species. Their most important role in living systems is to act as hormones. In human physiology and medicine, the most important steroids are cholesterol, steroid hormones, their precursors and metabolites